Organophotoredox Catalysis

Homogeneous Catalysis Homogeneous Catalysis

Microheterogeneous catalysis.

The catalytic effect of micelles, polymers (such as DNA, polypeptides) and nanoparticles, saturable receptors (cyclodextrins and calixarenes) and more complex systems (mixing some of the above mentioned catalysts) have been reviewed. In these microheterogeneous systems the observed changes in the rate constants have been rationalized using the Pseudophase Model. This model produces equations th...

Enantioconvergent catalysis

An enantioconvergent catalytic process has the potential to convert a racemic starting material to a single highly enantioenriched product with a maximum yield of 100%. Three mechanistically distinct approaches to effecting enantioconvergent catalysis are identified, and recent examples of each are highlighted. These processes are compared to related, non-enantioconvergent methods.

Bifunctional catalysis

Bifunctional catalysis concerns the use of low molecular weight, structurally defined molecules possessing two distinct functional groups to bring about new reactivity and/or selectivity in a reaction of interest. The reactions are typically polar addition reactions of pronucleophiles and electrophiles where, ideally, simple low-cost starting materials are converted into high-value, stereochemi...

aqueous phase thiosulfate removal using photo catalysis

removal of thiosulfate (s2o32-, 200 mg/l) from simulated wastewater samples was investigated under varying co-pollutants and ph conditions employing the titanium dioxide (tio2) mediated photocatalysis. for thiosulfate only studies higher substrate removal was noted at lower ph with a specific trend of ph 4 > ph 7 > ph 10. furthermore, near complete thiosulfate removal was also achieved at ph 4....